Measuring Enthalpy Change
Apparatus
- Thermometer to measure initial and final temperature
- Insulated container(plastic/Styrofoam) to prevent heat loss or gain during reaction
- Electronic balance(weigh mass of reactant)
- Measuring cylinders to measure volume of solvent
- The solute should be properly dissolved and the heat should be evenly distributed throughout the solution as best as possible. Hence a stirring rod should be used
Assumption
- 1ml of water or aqueous solution is equal to 1 gram
- Specific heat capacity of a dilute solution is the same as water=4.2J/g/K
- Specific heat capacity of a container is negligible
- It is also assumed that no heat is lost or gained to or from the solution
H=M Δ θ C,
Where m is the mass of the solvent, C is the specific heat capacity of water or dilute solution and Δθ is the change in temperature.